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Valorising lignin: A pathway to sustainable and high-performance biocomposites
University of Borås, Faculty of Textiles, Engineering and Business.
2025 (English)Doctoral thesis, comprehensive summary (Other academic)
Sustainable development
According to the author(s), the content of this publication falls within the area of sustainable development.
Abstract [en]

Lignin was chemically modified via acetylation to enhance its compatibility with polylactic acid (PLA) and the properties of resulting biocomposites. A microwave-assisted method was used to optimise the acetylation process by notably reducing its time and increasing its efficiency. Acetylation enhanced the interfacial adhesion between lignin and PLA, notably improving the mechanical, thermal, and moisture-repellent properties of the corresponding composites. The incorporation of Biomax® Strong as an impact modifier further increased ductility and impact strength, with blends containing 15–20 wt.% lignin and 5 wt.% impact modifier featuring a higher impact strength than those with lignin only. 

Building on these advancements, the development of fibre-reinforced composites was explored by combining PLA, microwave-acetylated lignin, and regenerated cellulosic fibres. Fibre inclusion provided an additional reinforcement, resulting in composites with a higher tensile strength, impact resistance, and thermal stability. Thus, microwave-assisted lignin modification combined with fibre reinforcement was identified as an efficient and sustainable route to lightweight high-performance materials showing potential for eco-friendly applications in the automotive and industrial sectors. 

By utilising lignin, a low-cost byproduct off the pulping industry, this study highlights an innovative strategy for transforming a traditionally underutilised material into a valuable resource for high-performance biocomposites. The successful integration of chemically modified lignin into PLA-based materials not only enhances their mechanical strength, impact resistance, and thermal stability, but also contributes to the advancement of sustainable manufacturing. By repurposing lignin, this research underscores its potential to play a key role in reducing the dependence on fossil-based materials, promotes circular economy principles, and enables the development of lightweight, durable, and eco–friendly composites for next-generation applications. 

Place, publisher, year, edition, pages
Borås: Högskolan i Borås, 2025.
Series
Skrifter från Högskolan i Borås, ISSN 0280-381X ; 156
National Category
Polymer Technologies
Research subject
Resource Recovery
Identifiers
URN: urn:nbn:se:hb:diva-33350ISBN: 978-91-89833-70-8 (print)ISBN: 978-91-89833-71-5 (electronic)OAI: oai:DiVA.org:hb-33350DiVA, id: diva2:1942320
Public defence
2025-04-25, C203, Allégatan 1, Borås, 10:33 (English)
Opponent
Supervisors
Available from: 2025-04-01 Created: 2025-03-04 Last updated: 2025-09-24Bibliographically approved
List of papers
1. Effect of lignin acetylation on the mechanical properties of lignin-poly-lactic acid biocomposites for advanced applications
Open this publication in new window or tab >>Effect of lignin acetylation on the mechanical properties of lignin-poly-lactic acid biocomposites for advanced applications
2023 (English)In: Industrial crops and products (Print), ISSN 0926-6690, E-ISSN 1872-633X, Vol. 202, article id 117049Article in journal (Refereed) Published
Abstract [en]

Bioplastics that possess characteristics like durability and low cost are desired for versatile applications in industries such as automotive manufacturing, marine transport manufacturing, aerospace applications, and the building industry. The automotive industry is an example of an industry that is now shifting towards a more focused approach addressing the issue concerning sustainability and the development of sustainable material. To achieve a lightweight and sustainable construction, one of the methods used by the automotive original equipment manufacturers is by substituting conventional fossil-based, non-renewable composites, and metallic materials with a bio-based alternative. One of the drawbacks with biobased polymers can be the poor interfacial adhesion, leading to poor mechanical properties when compares to conventional material. The aim of this research is to investigate if a low-cost by-product could be used as a component in a composite matrix material in the automotive industry to reduce the final weight and increase the non-petrochemical material usage of composite material without compromising the thermal and mechanicals properties demanded. In this research, lignin was chemically altered by esterification the functional groups to increase the compatibility with polylactic acid. The esterification was performed with the use of acetic acid anhydride and pyridine. To evaluate and determine the esterification, Fourier transform Infrared Spectroscopy was used. By blending the modified lignin with polylactic acid the intention was to improve the thermomechanical properties and the interfacial linkage between the components. The effects of lignin acetylation on the tensile properties, impact strength, and thermal stability and moisture repellence behaviour were investigated. According to the experimental results the modification of lignin, increased the impact strength for all the blends containing acetylated lignin compares to pristine lignin. The largest increase observed was for blends containing 20 wt% acetylated lignin and polylactic acid, which resulted in a 74% improvement compared with the blend composed of pristine lignin and polylactic acid. Similarly, the thermal stability was improved significantly with acetylation of the lignin. Moreover, the moisture repellence behaviour was also increased. The reason for the improved properties can be explained by the better interfacial compatibility between lignin and polylactic acid matrix. An increased thermal stability and a moisture repellent behaviour of the blends containing chemically modified lignin could be observed when compared with neat polylactic acid which makes the acetylation treatment of lignin a possible approach for the future of biocomposite production. 

Place, publisher, year, edition, pages
Elsevier, 2023
Keywords
Acetylation, Biocomposites, Impact toughness, Lignin, Polylactic acid, Costs, Lactic Acid, Mixing, Polyesters, Automotive industry, Blending, Construction industry, Esters, Fourier transform infrared spectroscopy, Sustainable development, Thermodynamic stability, Weathering, %moisture, Advanced applications, Automotive manufacturing, Bio-plastics, Biocomposite, Composites material, Low-costs, Modified lignins, Poly lactic acid, byproduct, chemical reaction, composite, equipment, mechanical property, sustainability, Impact strength
National Category
Composite Science and Engineering
Identifiers
urn:nbn:se:hb:diva-30307 (URN)10.1016/j.indcrop.2023.117049 (DOI)001023027100001 ()2-s2.0-85162265698 (Scopus ID)
Available from: 2023-08-14 Created: 2023-08-14 Last updated: 2025-09-24Bibliographically approved
2. Lignin-polylactic acid biopolymer blends for advanced applications – Effect of impact modifier
Open this publication in new window or tab >>Lignin-polylactic acid biopolymer blends for advanced applications – Effect of impact modifier
2024 (English)In: Composites Part C: Open Access, ISSN 2666-6820, Vol. 14, article id 100502Article in journal (Refereed) Published
Abstract [en]

In this study, lignin underwent chemical modification via acetylation of hydroxyl groups to enhance its interfacial connection with poly (lactic acid) (PLA). Further enhancement of the blend was attained by adding an impact modifier, Biomax Strong. Incorporating Biomax Strong into PLA-lignin blends resulted in improvements in material characteristics, particularly in impact strength and thermal stability. This blend exhibited a unique set of mechanical properties, characterized by a reduction in tensile modulus as well as an increase in ductility. This will allow a more versatile use of PLA in various applications. The observed improved impact strength highlights the synergistic effect of stress redistribution within the PLA matrix contributing to widespread applications of PLA based composites. This can clearly be observed for the compound containing PLA and 15 wt.% lignin, where the impact strength was approximately 15 kJ/m2. With the addition of 5 wt.% impact modifier, the impact strength increased by 60 %, reaching approximately 25 kJ/m2. This synergy effect reinforces the overall structure, improving the impact toughness behavior. The combination of Biomax Strong and lignin not only address the limitations of PLA but also introduces new opportunities for applications requiring a balance of impact strength, ductility, and thermal stability. These advancements indicate a promising future for composite materials in various applications.

 

Keywords
Lignin valorisation, Polylactic acid, Impact toughness, Acetylation, Biopolymer blend
National Category
Polymer Technologies
Research subject
Resource Recovery
Identifiers
urn:nbn:se:hb:diva-32608 (URN)10.1016/j.jcomc.2024.100502 (DOI)001294770700001 ()
Available from: 2024-09-25 Created: 2024-09-25 Last updated: 2025-09-24Bibliographically approved

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Johansson, Matilda

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