Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • harvard-cite-them-right
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Polymer rejuvenation of PET textile waste
University of Borås, Faculty of Textiles, Engineering and Business.
2020 (English)Independent thesis Advanced level (degree of Master (Two Years)), 20 credits / 30 HE creditsStudent thesis
Abstract [en]

Thermomechanical recycling of polyethylene terephthalate (PET) typically includes a decrease in the polymer´s intrinsic viscosity and therefore a reduction of the molecular weight. Consequently, thermomechanical recycling is usually a downcycling of the product. However current methods to increase the molecular weight such as solid-state polymerization or the usage of chain extenders are time consuming or introduce foreign molecules into the PET´s molecular chain. Thus, the aim of this work was to try to increase the molecular weight in the molten state in an extruder, to decrease the processing times. The processing times are reduced compared to the solid-state polymerization because in the molten state the movability of the polymer chain is increased. Moreover, no supplementary substances are added for the processing so that no foreign structures are introduced during reprocessing. Virgin PET pellets were extruded at 285°C, 290°C and 295°C set temperature and 2rpm, 4rpm, and 7rpm screw rotation rate. Afterwards the PET´s properties were investigated by measuring their intrinsic viscosities, conducting a 1H NMR and a DSC measurement. Additionally, pre-experiments were conducted to explore the possibilities of feeding industrial scrap polyester fabrics into the extruder. The polymer characterization showed that the intrinsic viscosity and therefore the molecular weight of the processed samples decreased with the parameters chosen for this experiment. Samples processed at 285°C and 7 rpm showed in the average the highest intrinsic viscosities and therefore the highest molecular weight of all processed samples. Additionally, the results of the 1H NMR and the DSC indicated degradation reactions such as thermal degradation and hydrolysis. Thus, further research is necessary to find an easily accessible recycling method for polyester textiles and reduce the amount of polyester textile waste. However, it is possible to feed long textile stripes into the twin screw extruder and reprocess it to a strand which is an important step for further recycling.

Place, publisher, year, edition, pages
2020.
Keywords [en]
PET, recycling, textiles, molecular weight
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:hb:diva-23819OAI: oai:DiVA.org:hb-23819DiVA, id: diva2:1468578
Available from: 2020-09-18 Created: 2020-09-18 Last updated: 2025-09-24Bibliographically approved

Open Access in DiVA

fulltext(3518 kB)1317 downloads
File information
File name FULLTEXT01.pdfFile size 3518 kBChecksum SHA-512
b09c054992bb6f05bdbf6b2dac1553f2284d7c36d8af24b8efc5857989c6cd383e1de392ddbcf59ec58839b3a7a3f3b513c4c408b991ef489bdd967349bb6cbe
Type fulltextMimetype application/pdf

By organisation
Faculty of Textiles, Engineering and Business
Engineering and Technology

Search outside of DiVA

GoogleGoogle Scholar
Total: 1321 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

urn-nbn

Altmetric score

urn-nbn
Total: 908 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • harvard-cite-them-right
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf