Nigeria is a tropical country with the over 150 million inhabitants out of which 70% is employed by agriculture. Bioethanol sticks out as the most important renewable biofuel and can be produced from lignocellulosic materials which include agricultural residues. Nigeria has the potentials of becoming a major biofuel ethanol producing country considering huge amount of agricultural wastes and residues generated each year, however, there is need for proper evaluation and planning before heavily investment in commercial production. This study focuses on the evaluation of the potentials of bioethanol production in Nigeria from various agricultural biomass and residues.