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Thermo‐mechanical properties of polyethylene composites filled with soapstone waste
Department of Chemical and Materials Engineering Pontifical Catholic University of Rio de Janeiro Rio de Janeiro Brazil.ORCID iD: 0000-0002-8497-1300
University of Borås, Faculty of Textiles, Engineering and Business. Swedish Centre for Resource Recovery, Faculty of Textiles, Engineering and Business University of Borås Borås Sweden;R&D Manager MuoviTech International Group MuoviTech AB Brämhult Sweden. (Swedish Centre for Resource Recovery)ORCID iD: 0000-0002-5725-586X
University of Borås, Faculty of Textiles, Engineering and Business. Swedish Centre for Resource Recovery, Faculty of Textiles, Engineering and Business University of Borås Borås Sweden.ORCID iD: 0000-0002-6596-8069
Department of Chemical and Materials Engineering Pontifical Catholic University of Rio de Janeiro Rio de Janeiro Brazil.
2023 (English)In: Journal of Applied Polymer Science, ISSN 0021-8995, E-ISSN 1097-4628, article id e55017Article in journal (Refereed) Epub ahead of print
Abstract [en]

In this study, soapstone waste originated from craftsmanship activities was used as an alternative filler (0–30 wt%) for a high-density polyethylene (PE) matrix. The aim of this paper is to understand the effect of the filler particles on crystallinity, thermal stability and thermo-mechanical properties of this newly developed composite material. Physico-chemical characterization was performed by x-ray diffraction (XRD) and Fourier-transform infrared (FTIR) spectroscopy. Thermogravimetric analysis (TGA), oxidation induction time (OIT) and dynamic mechanical thermal analysis (DMA) were performed to assess the effect of the filler on the themo-mechanical properties of PE. Thermal stability, measured by TGA, was enhanced, while OIT values reduced with filler content. A significant increase on the storage modulus of the composites (up to 148% in comparison with unfilled PE) was observed and this reinforcing effect was even more prominent at higher temperatures. XRD analysis revealed that the degree of crystallinity improved significantly with soapstone loading, which explains the substantial increase in stiffness observed. Increased crystallinity is also associated with higher strength, reduced residual stress, and better dimensional stability of end products, which can be particularly attractive for pressure pipe applications. 

Place, publisher, year, edition, pages
John Wiley & Sons, 2023. article id e55017
Keywords [en]
catalysts, copolymers, emulsion polymerization, morphology, nanoparticles, nanowires, and nanocrystals
National Category
Ceramics
Research subject
Resource Recovery
Identifiers
URN: urn:nbn:se:hb:diva-31141DOI: 10.1002/app.55017ISI: 001124723600001Scopus ID: 2-s2.0-85179988180OAI: oai:DiVA.org:hb-31141DiVA, id: diva2:1825026
Available from: 2024-01-08 Created: 2024-01-08 Last updated: 2024-02-01Bibliographically approved

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Kalantar Mehrjerdi, AdibSkrifvars, Mikael

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